A bit of a shameless plug, but I don't think I've put this down on "paper" in Alternate Cabinets yet. Also it has the advantage of getting into some of the weeds because there's
such fun to be had at the intra-departmental level too. The initial Cabinetry for my TL in progress
McGoverning, no spoilery changes over time here but the picture as of early 1973. For anyone interested.
McGovern Administration
McGovern Cabinet
President: George S. McGovern
Vice President: Philip A. Hart
Secretary of State: R. Sargent Shriver, Jr.
Secretary of the Treasury: John Kenneth Galbraith
Secretary of Defense: Cyrus Vance
Attorney General: Archibald Cox
Secretary of the Interior: Jesse Unruh
Secretary of Agriculture: Frank Morrison
Secretary of Commerce: Dwayne Andreas
Secretary of Labor: Leonard Woodcock
Secretary of Health and Human Services: Andrew Young
Secretary of Education: J. Terry Sanford
Secretary of Housing and Urban Development: George Romney
Secretary of Transportation: W. Graham Claytor
Secretary of Peace: Donald M. Fraser
Secretary of Veterans' Affairs: Gen. David M. Shoup, USMC (ret.)
"Cabinet-rank" positions
Director of Central Intelligence: Paul "Pete" McCloskey
Chairman of the Federal Reserve: Arthur Burns (replaced midway through 1973 by Andrew F. Brimmer)
Ambassador to the United Nations: Shirley Chisholm
United States Trade Representative: Lawrence "Larry" O'Brien
Director of the Arms Control and Disarmament Agency: John Sherman Cooper
Executive Office of the President
White House Chief of Staff: Gary W. Hart
Deputy White House Chief of Staff: Douglas A. Coulter
Office of Counsel to the President: Frank Mankiewicz
Deputy to the Office of Counselor to the President: Gene Pokorny
White House Counsel: Ramsey L. Clark
National Security Adviser: Paul Warnke
Deputy National Security Adviser: Robert Sherman
Director, Office of Management and Budget: Lester Thurow
Chair, Council of Economic Advisers: Edwin Kuh
Director, Office of Policy Development: Jean Westwood
Director, Office of Public Liaison: Anne Wexler
White House Communications Director: Frank Mankiewicz [1]
White House Press Secretary: Richard "Dick" Dougherty
United States Department of State[2]
Secretary: R. Sargent Shriver, Jr.
Deputy Secretary: George Ball
Undersecretary for Political Affairs: Philip Habib
Undersecretary for International Security Affairs: David L. Aaron
Undersecretary for Management: William "Bill" Macomber
Assistant Secretary for African Affairs: Patricia Roberts Harris
Assistant Secretary for East Asian and Pacific Affairs: Richard "Dick" Holbrooke
Assistant Secretary for European Affairs: George Vest
Assistant Secretary for Inter-American Affairs: William G. Bowdler
Assistant Secretary for International Organization Affairs: Charles W. Mayne
Assistant Secretary for Near Eastern and South Asian Affairs: Alfred "Roy" Atherton
United States Ambassador to the Soviet Union: Robert S. "Bob" Strauss
United States Representative to the People's Republic of China: Arthur W. Hummel, Jr.
United States Ambassador to India: Chester Bowles [3]
United States Ambassador to the United Kingdom: Kingman Brewster, Jr.
United States Ambassador to France: Pierre Salinger
United States Ambassador to West Germany: Walter J. Stoessel, Jr.
United States Ambassador to Mexico: Edward R. Roybal
United States Ambassador to Brazil: Lt. Gen. Vernon Walters (ret.)
United States Ambassador to Israel: Kenneth B. Keating
United States Ambassador to Iran: Talcott W. Seelye
United States Ambassador to Saudi Arabia: James E. Akins
United States Ambassador to South Vietnam: John Gunther Dean
United States Ambassador to Cambodia: Daniel Patrick Moynihan [4]
United States Ambassador to Bangladesh: Archer Blood [5]
United States Department of the Treasury
Secretary: John Kenneth Galbraith
Deputy Secretary: Paul A. Volcker, Jr.
United States Department of Defense
Secretary: Cyrus Vance
Deputy Secretary: Townsend Hoopes II
Undersecretary for Policy: John D. Holum[6]
Undersecretary for Research & Engineering: Harold Brown
Undersecretary for Intelligence: Robert C. "Bob" Komer
Secretary of the Navy: Otis G. Pike
Secretary of the Army: Charles E. "Charlie" Bennett
Secretary of the Air Force: David S. Lewis, Jr.
United States Department of Justice
Attorney General: Archibald Cox
Deputy Attorney General: Clifford L. Alexander, Jr.
Solicitor General: John Doar
[1] Frank's wearing two hats in consequence of his central role with the administration's brains trust
[2] Though he doesn't have a formal title just yet, the senior administration bosses are maneuvering to give Clark Clifford a special ambassadorship that would in effect make him "arms control czar" for the administration, even though the subject-matter post at ACDA belongs to the retired liberal-Republican, anti-Vietnam senator from Kentucky John Sherman Cooper
[3] Returns for a hat trick
[4] Moynihan and John Kenneth Galbraith were close personal friends (JKG was actually close friends with several people whom he disagreed with even more sharply on policy, most famously William F. Buckley, and here despite Moynihan's association with Nixon they find a job for DPM even if it's a hardship post)
[5] Have I mentioned that this is pretty much the most Indophilic US administration in American history, even compared to JFK's?
[6] The McGovern administration beats OTL's Carter administration to the punch and sets up the subject-matter Undersecretaries at DoD