What it says on the tin. Starting in 1903ish, what can a rocket program (started for whatever reason) do with a modest but steady amount of funding? What can they get done by 1910? 1920? 1930? 1940?
Turpentine and nitric acid are fine enough rocket fuels and available in large quantitis since the mid 1800s. It's even hypergolic thus saving you having to come up with an ignition system.
The downside is that it's hypergolic, and the nitric acid will eat the tank if you let it stay for an extended amount of time, though there's nothing really preventing them from coming up with "inhibited" nitric acid.
The RFNA of 1945 was hated by everybody who had anything to do with it, with a pure and abiding hatred. And with reason. In the first place, it was fantastically corrosive. If you kept it in an aluminum drum, apparently nothing in particular happened —as long as the weather was warm. But when it cooled down, a slimy, gelatinous, white precipitate would appear and settle slowly to the bottom of the drum. This sludge was just sticky enough to plug up the injector of the motor when you tried to fire it. People surmised that it was some sort of a solvated aluminum nitrate, but the aversion with which it was regarded was equaled only by the difficulty of analyzing it. If you tried to keep the acid in stainless steel (SS-347 stood up the best) the results were even worse. Corrosion was faster than with aluminum, and the acid turned a ghastly green color and its performance was seriously degraded. This became understandable when the magnitude of the change in composition was discovered. Near the end of 1947, JPL published the results of two acid analyses. One was of a sample of RFNA fresh from the manufacturer, which had scarcely started to chew on the drum in which it was shipped. The other was a sample of "old" acid, which had been standing for several months in a SS-347 drum. The results were eloquent And, if my own experience is any criterion, there was a bit of insoluble matter of cryptic composition on the bottom of the drum. Acid like that might have been useful in the manufacture of fertilizer, but as a propellant it was not.
As it turned out, the type M-A gradually edged out the others, and is now the nitric acid oxidizer.* The engineers call it IRFNA, inhibited Red Fuming Nitric Acid, and very few of the current crop are even aware that there ever was another sort —or of what "inhibited" means. A few years ago I saw one alleged rocket engineer fill a stainless steel tank with RFNA without any HF in it —and then wonder why his acid turned green.
I did read that funny little book. And i'm aware of just how much of a bit** it is to work with, it's just the "simplest" fuel/oxidizer combo to start with at that time, by no means is it good or safe. It should be ok to do sounding rocket tests with it, not to be used as something to push a dog or ape over the Karman Line, nevermind a human.Nitric Acid wasn't really useful as an oxidizer until it was stabilized in the 50s after massive amounts of research involving at one point every propellant chemist in the US. Turns out nobody really knew anything about the stuff. Suggest reading IGNITION! An Informal History of Liquid Rocket Propellants by John D. Clark for a good rundown on how that worked out.
To quote the opening of the chapter regarding nitric acid:
On solid rocket motors, it's a bit surprising to read just how much we are not sure how we got where we are today
https://www.nasa.gov/centers/dryden/pdf/88635main_H-2330.pdf
it's just the "simplest" fuel/oxidizer combo to start with at that time, by no means is it good or safe
I don't think nitric acid is that much worse than nitrogen tetroxide, which after all has flown in...well, actually nearly every American crewed spaceflight, and powered the Titan and Long March booster rockets used for the Gemini and Shenzhou missions. Is it fun, no, could it be made to work, yes.I did read that funny little book. And i'm aware of just how much of a bit** it is to work with, it's just the "simplest" fuel/oxidizer combo to start with at that time, by no means is it good or safe. It should be ok to do sounding rocket tests with it, not to be used as something to push a dog or ape over the Karman Line, nevermind a human.
I don't think nitric acid is that much worse than nitrogen tetroxide, which after all has flown in...well, actually nearly every American crewed spaceflight, and powered the Titan and Long March booster rockets used for the Gemini and Shenzhou missions. Is it fun, no, could it be made to work, yes.
Yes, and that doesn't actually have anything to do with my point, which is that IRFNA is perfectly fine for launching dogs, apes, or even people with once you figure it out; it's no worse, from a handling standpoint, than other oxidizers that are routinely used in human spaceflight. And we're not exactly on a short timeline here, so someone's going to figure out inhibition sooner or later.It was made to work by putting the entirety of the US propellant research community on it for several years and was still made by a few lucky coincidences, the research into this also incidentally led to Dinitrogen tetroxide being figured out (Being a major component of RFNA) and replacing RFNA.
It took Hercules Powder company from starting in the 1940s, a decade or so to get reliable nitrocellulose and nitroglycerin doublebase grains that could burn longer than a few secondsI'll leave to the experts to judge how much earlier Goddards motor of 1918 could have been made. Or something of similar performance.
Making it work as reliably as today but in the early 1900s would not be that easy, ideally you use it for the first parts of the program and then along the way, after you hopefully looked into the chemistry of rocket launching, you ditch it for better, easier to handle fuel/oxidizer combos. Kerosine and liquid oxygen will not eat away your fuel tank made out of questionable steel while they're just about as hard/easy to source.I don't think nitric acid is that much worse than nitrogen tetroxide, which after all has flown in...well, actually nearly every American crewed spaceflight, and powered the Titan and Long March booster rockets used for the Gemini and Shenzhou missions. Is it fun, no, could it be made to work, yes.
Yes, and that doesn't actually have anything to do with my point, which is that IRFNA is perfectly fine for launching dogs, apes, or even people with once you figure it out; it's no worse, from a handling standpoint, than other oxidizers that are routinely used in human spaceflight. And we're not exactly on a short timeline here, so someone's going to figure out inhibition sooner or later.
last stand of empirical testing, the nice way of people with degrees saying 'You'all hold my Beer, I gotta idea'