Think this is pretty unlikely, to be honest. Stalin would not front the Soviets into such a situation.
If we suggest something like Volshirov decides to hit Poland on what he thinks will be "Day 1" but it is actually "Day -7", Poland will DoW the Soviet Union and the UK and France are probably NOT going to DoW the Soviets on this spot--if Germany attempts to move in afterward, France and the UK are going to have to threaten war unless Germany pulls out. Now, given the situation, it is possible that Poland goes down before France and the UK actually DoW Germany, but the distinction doesn't mean much with the whole Sitzkrieg in the West in OTL.
The major change, however, is that Finland is going to recieve Allied Support and bombing Baku will go forward. If this results in a Triangle War, when Germany attacks the Soviet Union, I would expect Germany-Soviet Union to very quickly emerge as the nastiest of the three coalitions, and the one war that will not get peaced out of.
I'm still unsure how the Triangle would play out.