Interesting, why do you think this is?
Ahh... Because it is?
In other words. Copper smelting can happen by accident when you build a hot enough fire on bare rock that happens to be copper ore. Some copper ores are natural arsenical, and smelting them gives you a very primitive bronze. Once you've developed the idea of smelted metal tools, it's easier to try smelting other ores and see what happens (especially if you don't have good copper resources, say).
Iron is much, much harder to melt. You can't get it to happen by accident. So why would you try, unless you already are smelting something easier (e.g. copper, silver or gold).
Now. The Mesoamericans and Andeans DID smelt copper, silver and gold. So the idea of trying something with iron is certainly possible.
Note that
a) America does not have good sources of tin - at least anywhere near copper sources - so they're not going to be coming up with copper-tin bronze
b) early iron, until you spend a few hundred years working with it, and learning how to do it right, is not as useful as bronze for tools and weapons. The Hittites, e.g., probably started playing with iron because it was better than copper and imported tin was EXPENSIVE. However, Iron weapons/tools, even early versions, still beat copper ones. So there is a good route there for Mesoamericans or Andeans. Start with lousy tools, and spend several hundred years learning how to deal with iron.
c) OTOH, the Mesoamericans did not, as I understand it, use copper for weapons, or even very much as tools. Unlike Mesopotamia, say. So there's just not as much pressure to find something 'better'. What they DID use metals for, a lot, was decoration, jewelry, and iron (short of stainless steel) just isn't 'pretty'.