The earliest camera techology was photpolymerisation of bitumen. Use a camera obscura and severl months to get landscape pictures. Discover the technique by accident somehow?
A camera obscura is a hole in a way opposite a view. A bitumen photopolymerisation negative is when UV from sunlight polymerises olefins (cracked alkanes from an oil deposit that has been thermally heated to 'crack' the alkanes) and then the polymerised olefins resist being disolved by light weight alkanes like propane, butane, and pentane, leaving the polymerised olefin material behind as a negative and as the positive, too, come to think of it. Someone would have to coat a wall opposite the wall with the hole in it, perhaps as water proofing or something, and then leave the image alone for a few months and let it 'etch' itself in the bitumen. When he comes back he figures he's got a commercial product there and starts making images of cities and mountains to sell as murals for walls.