5th Executive Council
| Office | Officeholder | Political Party | Home State | Preceded by | Followed by |
| Executive Chair | Alexander Hamilton | Federalist | New York | Thomas Jefferson | REDACTED |
| Constitutional Chair | Thomas Jefferson | Democratic-Republican | Virginia | Alexander Hamilton | REDACTED |
| Chair of State | James Madison | Democratic-Republican | Virginia | John Adams | REDACTED |
| Chair of the Treasury | John Adams | Federalist | Massachusetts | James Madison | REDACTED |
| Chair of Justice | James Marshall | Federalist | New York | James Marshall | REDACTED |
| Chair of the Interior | James Monroe | Democratic-Republican | Virginia | James Monroe | REDACTED |
| Chair of the Army | John Quincy Adams | Federalist | Massachusetts | John Paul Jones | REDACTED |
| Chair of the Navy | William Bainbridge | Federalist | New Jersey | John Paul Jones | REDACTED |