I suspect not a great number; the Witwatersrand gold rush was in 1886, just fourteen years before the Second Boer War so none who had been born to Uitlanders who had rushed into the republics as a result would have been old enough to vote anyway, and the miners were disproportionately composed of single men, or men whose wives were not with them.
True, but there would have been a few who made their way to the Transvaal before the gold rush.
Apparently Scots were used often as priests and teachers by the Boers, but I have the feeling they were generally assimilated.
I met a guy once called Lyle McPherson who was one of the most Afrikaans people I have ever met.