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An ideal I'm considering for a TL project, but I don't know much about the topic: What European powers would be most likely to establish a colony in the Patagonia region prior to the expansion of Argentina and Chile? If such an establishment is possible, when is it most likely to happen?

I'm sorry it's not more specific, but I'm not really sure if this ideal is possible at all, so am trying to keep it open to all options.
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