We just returned from 12 weeks in Ecuador and Peru. We spent a lot of time in museums and well as at archaeological and naturalist sites. We saw one display at the Machu Picchu Museum in Cuzco that discussed the development of an effective bismuth allow of bronze. This alloy did not get re-invened until the 1880s in Germany. So I googled this and found a number of corroborating citations. The below is from "The Christian Science Monitor
http://www.csmonitor.com/1984/0216/021617.html
The Late Horizon cultures (immediately Pre-Inca and Inca) developed an excellent bismuth-tin-copper alloy that was very strong and useful. This alloy was not re-discovered until the 1880s. Earlier attempts during bronze age resulted in an extremely brittle alloy.
"...rhis appears to be the first known use of bismuth in bronze anywhere in the world. Moreover, it is used in a way that takes advantage of the new properties bismuth confers without suffering the drawback of making the alloy brittle.
Gordon and Rutledge explain that this reflects the microscopic structure of the alloy. The metal is made up of microscopic grains. Ordinarily, bismuth-containing grains penetrate grains of copper-tin - a penetration which makes the metal brittle.
x In modern copper-based bismuth-containing alloys such as brass the addition of zinc prevents such grain-boundary penetration. In the Inca knife handle, the addition of an unusually high amount of tin also inhibits grain-boundary penetration.,,"