Louis XIV has a Second Son

Other than the Dauphin, Louis XIV gave birth to two other male children Philippe (b 1668) and Louis François (b 1671). What if one of them survived. Who would they marry and would he become King of Spain in 1700?
 
Likely the King of France will push for a match between his second son and Archduchess Antonia. If he can get her as daughter-in-law accepting the total separation between France and Spain (who will be asked by both the HRE and the King of Spain), who his son will rule only as Antonia’s husband and will compensate Austria (accepting who Milan will go to Austria and likely Leopold will ask also Netherlands and a wedding between an Archduchess and the next prince of Asturias or the Duke of Bourgogne, who was the eldest son of the Dauphin or both) I can see a pacific Bourbon takeover in Spain
 
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