@ArtisticCritic TBH : I like your scenario. IMO a much better way to "trigger" an alternate WW I.
Though I don't really see an "appeasement" between Serbia and A-H-C (ITTL), as the the new "C", Croatian Kingdom, would deny Serbia, what its looking for. Also I don't see Russia letting pan-slavism go, as it also served their other important objective in the reagion : access and control of the straits (Bosporus and Dardanells).
There could be rather an additional "alliance" messing up diplomacy even more compared to IOTL : between Italy, Serbia and Russia, dividing the Balkan and A-H-C under the three as "zones of influence", with Serbia probably being the most minor part of it, more or less an "agent" of russian interests.
Italy gets Croatian, Tyrol, dalmatian coast, Albania, Greece (without "macedonian" parts but all/most of the agean isles), perhaps also a dismanteled Hungary.
Russia gets Galicia, Slovakia, Ruthenia, maybe also Czechia with Romania and Bulgary as their puppets, with Romania propped up with large parts of Hungary, Bulgaria with the macedonian parts of Greece (access to the Mediterrainian. Oh, and ofc Constantinople and the Dardanells with land strips around as a Russia-controlled puppet "New Byzanthium", nominally neutral-independant.
Serbia gets Bosia-Herzegowina, the Banat, maybe some parts of Albania and Montenegro.
France in a way would bound to it by the Franco-Russian alliance.
Germany, due to unavailability of anyone else, would most likly stick with the alliance with A-H-C. Also, as the "Schlieffen"-concept becomes even more unrealistic will gear up its military/army expenditures and develop another "concept", which would most likely rely heavily on defense ( propping up fortresses/border fortifications) in the west as well as in the east.
To avoid a "counter-Schlieffen" aka France marching through Belgium it would possibly try to "enforce" the belgian guarantee by a set of sturdier treaties, clearly threatening any offender of Belgium with military as well as economic sanctions. And in that respect will seek closer ties with Britain.
About a possible detention between Germany and Britain :
It should be kept in mind, that 1n 1913 GB and Germany signed an agreement of dividing the portuguise colonies between them. And found an agreement about the Bagdad-railway also in summer 1914 (can't remember the exact date right now). Their relations WERE improving alteady in 1914 with Germany having more or less accepted the "loosing" of the naval arms race.