Earlier development of TNT or dynamite

TNT was first prepared in 1863 and dynamite patented in 1867 but what if one or both had been developed by say 1801, what effects does that have?
 
TNT was first prepared in 1863 and dynamite patented in 1867 but what if one or both had been developed by say 1801, what effects does that have?
The problem is you'd have to massively advance chemistry for this to work.

Nitrated organics are notoriously unsafe to handle unless the acids used are very, very pure.

As for nitroglycerine (the base of dynamite), it's notoriously tricky even IF you have good chemistry (which is why the soaking it into diatomaceous earth making dynamite was such a huge advance).

So.
2 options
1) someone discovers these compounds too early and probably dies in the resulting explosion. Perhaps he even sells a little, and his customers die. Interesting question whether people say 'wow, this is powerful, let's see if we can make it work', and eventually get a useful product 5 years early, or if the whole idea is totally discredited and it takes LONGER to develop them.

2) science in general, and chemistry in particular, advance by 50 years over OTL. In which case, dynamite is the least of your changes.
 
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