The Ariane-4 has the same payload as the Soyuz the Russians are using for their manned space vehicles. And although Ariane-4 was not officially manrated, its reliability had reached such high levels that it would have been only a matter of calling it manrated.
That why i didnt understand the retirement of the Ariane-4, as they both served a different portion of the market, the 4 being medium lift and the 5 being heavy lift.
I did the statistics (using Astronautix) one day.
From 1979 to 2003, the Ariane 1 / 2 / 3 / 4 family failed seven times (in 1980, 1982, 1985, 1986, 1990 and two times in 1994, a very bad year).
Five failures were traced to the HM-7 cryogenic stage - the very stage you don't need for low Earth orbit flight, isn't it ?
So two failures remain: the 1980 and 1990 ones.
The 1980 failure happened on the second test flight; destructive pogo on the first stage, which never happened again.
The 1990 failure is so dumb it is hilarious. At the Ariane plant of Les Mureaux, near Paris, some distracted or silly technician forgot a cloth into a Viking cooling tube. Noone noticed it, the tube was bolted to the Viking, the Viking went to Ariane, and Ariane to the Kourou launch pad.
The rocket took off, the cloth made the engine overheating and losing power. The others seven (it was a 44L with podded engines) tried to fill the gap; the rocket veered off course right from the launch, missed the top of its launch tower*** - and a major disaster - by only two meters (!), veered off further, and was destroyed, together with 500 million dollars worth of Japanese communication satellites.
Space balls !
*** top of the launch tower was found to be sooted and scorched black by the engines. Had Ariane hit the tower, it would have exploded into a nasty cloud of toxic, hypergolic propellants.
It happened to the Soviets in 1969 with a Proton; it happened to the Air Force Vandenberg pad in 1986 with a Titan 34D. Very ugly disasters !