Nuclear weapons are hard. They require large amounts of modern physics. Significant amounts of modernish math. Lots and lots modern chemistry and probalby industry. Lots of modern money.....
Can't argue with any of that, really. But is it even remotely possible to do without waiting for the theory? I've been attempting to construct a timeline where someone (Wilhelm Wien seems a good bet) invents a mass spectrometer in the late 1890's (i.e. about 20 years early), which allows the Curies to discover radioactive isotopes while they're refining pitchblende and discovering all sorts of good stuff in the residue. This would further allow Rutherford, who was discovering radioactive decay and the half-life at the same time, to demonstrate that different isotopes have very different half-lives and decay paths, and may even advances his theoretical work on the neutron.
Shortly afterwards, around 1906, Pierre Curie is killed in a lab explosion when in experimenting with techniques to separate out isotopes he accidentally manages to concentrate enough U-235 to start a small chain reaction. In the aftermath, other experimenters (who?) try to recreate the accident under more controlled conditions and (doubtless after a few more accidents) after a few more experiments manage to produce a rule of thumb estimate for things like the critical mass of U-235 and how it's affected by things like the shape and purity of the metal.
A few more years pass, and a skipload of cash, and somebody hits on a way of producing a very crude, gun type bomb, again by pure trial and error. The engineering has now run way ahead of the theory, but doubtless the likes of Rutherford and Marie Curie are working hard to catch up.
Is this at all doable, or is it pure ASB? It's the only way I can think of of getting a nuke by WW1 without a ridiculously early POD.
And if it is delivered by Zeppelin, is there any chance at all of an accidental thermonuclear reaction if it goes off next to, or even inside, the hydrogen envelope?