A Nuclear Century III
The Philosopher Stone
And yet surely to alchemy this right is due, that it may be compared to the husbandman where of Aesop makes the fable, that when he died he told his sons that he had left unto them gold buried under the ground in his vineyard: and they digged over the ground, gold they found none, but by reason of their stirring and digging the mould about the roots of their vines, they had a great vintage the year following: so assuredly the search and stir to make gold hath brought to light a great number of good and fruitful inventions and experiments, as well for the disclosing of nature as for the use of man's life.
Sir Francis Bacon's The Advancement of Learning
The shy "Lunatick" mentioned last time, Henry Cavendish lived very much up to the Lunar Society's nickname for its members. He was an English scientist who made pioneering investigations in chemistry and used a torsion balance experiment, devised by John Michell, to make the first accurate measurements of the mean density of the Earth and the strength of the gravitational constant and also almost as eccentric as he was brilliant.
Cavendish noticed that Michell's apparatus would be sensitive to temperature differences and induced air currents so he made modifications by isolating the apparatus in a separate room with external controls and telescopes for making observations.
He also carried out pioneering work on electricity, but much of his work was not published in his lifetime, and only became widely known when Cavendish’s papers were edited and published by James Clerk Maxwell in 1879. However he did publish his findings in regard to the phenomenon of "The Restoration of Spend Phlogiston trough Uranium Rays”.
Cavendish could afford not to publish his results, because he did not have to make a living out of science. Born on 10 October, 1731, at Nice, in France, Cavendish was the son of Lord Charles Cavendish, and grandson of the both 2nd Duke of Devonshire (on his father’s side) and the Duke of Kent (on his mother’s side). His father, himself a Fellow of the Royal Society, was administrator of the British Museum. Henry Cavendish studied at Cambridge University from 1749 to 1753, but left without taking a degree (not particularly unusual in those days), and studied in Paris for a year before settling in London. He lived off his private fortune, and devoted his time to the study of science. Apart from his scientific contacts, he was reclusive, and published little, although he used some of his money to found a library, open to the public, located well away from his home. He was once described as “the richest of the wise, and the wisest of the rich.”
Among his unpublished discoveries, Cavendish anticipated Ohm’s Law and much of the work of Michael Faraday and Charles Coulomb. He also showed that gases could be weighed, and that air is a mixture of gases, not a pure substance. One of the great English scientists of the second half of the eighteenth century, Cavendish, among other things, discovered hydrogen gas. But for a long time not many people knew just how clever he was, because as well as being almost unbelievably rich, so that he could do whatever he liked, Cavendish was also incredibly shy, and he didn’t bother to tell the world about most of his amazing discoveries for most of his live. But he did write down accurate notes of all of his experiments, which were discovered after he died.
His father was only the fourth out of five brothers and six sisters, so he didn’t inherit a title himself; but he was certainly aristocratic, and he inherited a lot of money. Henry’s father, Charles Cavendish, had married his mother, Anne de Grey, in 1729. Anne was only 22, and she was ill almost for the rest of her short life, with what seems to have been tuberculosis. Henry was born in Nice, in 1731, where his parents had gone to escape from the English winter, and his brother Frederick was born in England in 1733. Before the end of that year, their mother was dead. Charles Cavendish never remarried, so Henry never really had a mother, which may partly explain why he grew up to be such a peculiar man.
In 1738, Charles Cavendish sold his country estate and moved to London with his two sons, in the year Henry had his seventh birthday. Both boys went to school in London, then on to Peterhouse (a Cambridge college, but never called Peterhouse College). After Henry had left Peterhouse in 1753, Frederick fell from an upstairs window and suffered a head injury which caused permanent brain damage. He was well enough to manage a fairly normal life, with the help of servants, but after the accident he could not do anything very intellectual.
But Henry was clever enough for at least two ordinary people. He went on the usual Grand Tour with his brother, then settled down at the family house in Great Marlborough Street to be a scientist. He wasn’t interested in anything else at all, and although he received an allowance from his father of £500 a year, he hardly spent any of it. He only ever owned one suit of clothes at a time, which he wore every day until it was worn out. Then he bought another in exactly the same style, even though this got more and more old-fashioned as time passed.
Later on, after his father died in 1783, when Henry was 52, and he had a huge fortune, Cavendish carried on just the same. He ate mutton every day, and one day when he was expecting some scientific friends for dinner (he only had scientific friends), his housekeeper asked him what to serve. “A leg of mutton,” he replied. She said this would not be enough. “Well then,” he said, “get two.”
One day, his bank manager called round. He was worried because Henry had £80,000 in his current account. This was a vast fortune when a fashionable gentleman could live comfortably on £500 a year, but Cavendish was so rich he had forgotten about it. The banker asked Cavendish if he would like to invest the money more profitably. Cavendish was so angry at having been bothered about the money that he told the bank manager to go away at once, or he would close the account.
Rather nervously, the manager asked if Cavendish might like to invest just half the money. To shut him up, Cavendish said the banker could do what he liked with the £40,000 as long as he went away at once. The honest banker put the money into safe investments, where it made a profit and made Henry Cavendish even richer.
When he died, in 1810, Cavendish was worth almost exactly a million pounds. This would be equivalent to about a billion pounds today. He left all the money to relatives, and one of their descendants, William Cavendish, the seventh Duke of Devonshire, used some of the fortune to establish the “British Nuclear Radiation Company”. It was mostly meant to cash on the well known health effects of nuclear radiation but its research laboratory was responsible for some key discoveries leading to the modern nuclear energy technology as well. The only thing Henry Cavendish however spent money on was houses, to give himself space for his scientific work, and laboratory equipment to put in the space. After his father died, he rented out the house in Great Marlborough Street, and bought one at Clapham Common, which was then a quiet, leafy area just outside the bustle of London.
Cavendish only ever went out on scientific business. He became a Fellow of the Royal Society in 1760. He hadn’t done any real science then, but in those days rich people who were interested in science were welcome as Fellows even if they hadn’t actually done much science. Cavendish often went to their meetings. But even there he was so shy that if he was late he would wait quietly outside the door until somebody else came along, so that he wouldn’t have to go into the room on his own. He also went to dinner with other Fellows, who had a dining club that met regularly.
Most of the time, Cavendish only communicated with his servants by writing notes to them, and several people who knew him have written how if he came across a woman he did not know he would cover his eyes with his hand and run away. But in the summer he would travel round Britain in a coach, visiting other scientists and studying geology.
The reason Cavendish was regarded as “the wisest of the rich” was thanks to his work in chemistry. This was because he did publish a lot of papers on this work, although he didn’t publish all of it. At the time, nobody knew about most of his other work, even though it was just as important. For example, in electricity we now know that Cavendish was the first person to discover what is known as Ohm’s Law, but he never told anybody, so Ohm had to discover it again later.
In the 1760s, Cavendish started experimenting with gases, carefully following Black’s example by measuring and weighing everything as he went along. He found that the gas given off when acids react with metals is different from ordinary air, and from Black’s fixed air. It burned very easily, and Cavendish called it “inflammable air;” we call it hydrogen. Indeed, the gas burned so vigorously that Cavendish soon decided that it must be pure phlogiston. He also studied Black’s fixed air and the properties of Priestley’s fizzy mineral water. But in 1767, probably because he read Priestley’s book on electricity, he dropped his chemical experiments, and turned his attention to electricity. Hardly any of this work was published at the time, which was a great loss to science. Among other things, Cavendish proved that electricity obeys an inverse square law. This is now known as Coulomb’s Law, because Coulomb was the first person to publish it. Cavendish also measured the strength of the electric force very accurately.
Then, in the 1780s Cavendish went back to chemistry. He’d got interested in the way that air seems to be lost when things burn in it. For example, if a lighted candle is stood on a little island in a bowl of water, with a glass jar over the top, as he candle burns the level of water rises. This is because the volume of air is shrinking. About a fifth of the air disappears in this way before the candle goes out. We say that this is because one fifth of the air is oxygen, and the oxygen gets used up in burning.
Cavendish still tried to explain what was going on in terms of phlogiston, even though Priestley had already discovered oxygen and found that it makes up about a fifth of ordinary air. The explanation got horribly complicated and is exceedingly difficult to understand. Nevertheless a little detour into phlogiston theory might be in order.
This obsolete scientific theory postulated that a fire-like element called phlogiston, contained within combustible bodies, is released during combustion. The name comes from the Ancient Greek phlogistón (burning up), from phlóx (flame). It was first stated in 1667 by Johann Joachim Becher. The theory attempted to explain burning processes such as combustion and rusting, which are now collectively known as oxidation.
Phlogisticated substances are substances that contain phlogiston and dephlogisticate when burned. In general, substances that burned in air were said to be rich in phlogiston; the fact that combustion soon ceased in an enclosed space was taken as clear-cut evidence that air had the capacity to absorb only a finite amount of phlogiston. When air had become completely phlogisticated it would no longer serve to support combustion of any material, nor would a metal heated in it yield a calx; nor could phlogisticated air support life. Breathing was thought to take phlogiston out of the body.
What is important here is that Cavendish carried out experiments in which oxygen (dephlogisticated air, to him) and hydrogen (pure phlogiston, he thought) were exploded together in a metal container, using an electric spark. Apart from making a satisfying bang, the experiment at last started chemists, although not Cavendish, thinking along the right lines about oxygen, and what happens when things burn. Hydrogen and oxygen combine to make water. Cavendish found that his two gases always joined together in the same proportions to make water. He weighed everything carefully before and after each experiment, so he found that the weight of water produced was exactly the same as the weight of gas lost. Putting the numbers in, he found that 423 measures of “phlogiston” combine exactly with 208 measures of “dephlogisticated air” to make pure water with no gas left over.
This was a key moment in chemistry because it showed that water is a compound substance. It is somehow made by two other substances joining together, not any old how but joining together always in exactly the same proportions. Actually 2:1 exactly, we now know, for hydrogen and oxygen combining to make water.
This was the first step towards understanding how atoms combine to make molecules. Cavendish couldn’t take the step properly because he was stuck with the idea of phlogiston. But his discovery was immediately picked up and developed in France, by Antoine Lavoisier. In 1785 Cavendish was able to remove both oxygen and nitrogen gases from air and was left with a tiny amount of unreactive gas, argon. However he didn't pursue this line of thought any further. It does however highlight his skill at rigorous quantitative experiments. He used calibrated equipment, obtained reproducible results, repeated those experiments and averaged the results, and always tried to allow for sources of error.
While Lavoisier and others took his insight into the nature of air forward, Cavendish carried on experimenting, going to scientific meetings and dinners, and publishing some, but not all, of his discoveries. Somewhere around 1790 he overheard Bennet and his observation made with the gold leaf electrometer and uranium.
In order to probably study the mineral's capabilities he ordered a box of pitchblende from a mine in Joachmistahl. Money was never a particular concern to him, and scientific curiosity trumpeted everything else.
The first step he took was to device a way to measure the strength of the radiation emitted by the samples by modifying Bennet's equipment. An electrostatic charge was placed upon two gold foil leaves, causing them to repel. As radiation strikes the meter the foil leaves lose their charge and start to droop.
This droop could be measured and a rate could be established. The weight of its leaves permanently established the instruments calibration, when built as specified with a properly sized scale. Once the preparations were made, he found that indeed the amount of uranium was proportional to the radiation measured but he also found that pitchblende was more radioactive than it should be given the uranium it contained. He correctly assumed that it was probably containing another (or more) radioactive elements.
Klaproth came to the same conclusion but on a different way. After finding uranium he naturally wondered if there were other radioactive elements. The first place he went to look at was the remaining pitchblende. There was no established theory explaining radioactivity but it sounded intuitive to him that whatever unknown factor responsible for the radioactivity might also lead to the existence of other types of these minerals.
Nature seemed to prove him right. The uranium free pitchblende was measurably radioactive. He still had to use a photo plate since Cavendish didn't publish his findings much later and Bennet had gone into internal exile (1).
Over the next decade and under tremendous difficulty Klaproth managed to fulfill his personal magnum opus, to isolate two new elements, Arminium (2) and the highly radioactive radium which only occurred in trace amounts. We will take a closer look at his work at a later point, but we will keep in mind that he found that the very rare, seemingly immensely useful element Arminium had the bad habit of turning into lead, which promoted him to comment that he found the “Stein der Narren/The Fool Stone.”
As for Cavendish his continued systematic studies of the various chemical compounds indicated that the strength of the radiation depend only on the amount of uranium not on their composition. As later chemist found, chemical compounds of the same element generally have very different chemical and physical properties.
In Cavendish's case one uranium compound was a dark powder, another a transparent yellow crystal, but what was decisive for the radiation they gave off was only the amount of uranium they contained. thus future generations of researcher had to accept that the ability to radiate did not depend on the arrangement of the atoms in a molecule and subsequently must be linked to the interior of the atom itself.
Now that the basics for his experiment had been secured he could begin his investigation into the uranium rays on the gold leaf electromter. The first intriguing discovery he made was that the radiation was effecting the air and not the gold leaves themselves. This was possible thanks to the use of a sophisticated vacuum pump. Once he established that the rays were affecting the air Cavendish wanted to see how and if their physical properties changed. This lead to some fascinating discoveries but none of them was as important as the following.
Cavendish left a glass filled with nitrogen (known to him as burnt air or dephlogisticated air) and a sample of radioactive material alone over a consiberable time. He wanted to see if and how many lasting changes may have happened. To his surprise he found that the rays somehow had restored the phlogistic property as he gained the same basic results as in his earlier hydrogen/oxygen experiment (only in a much smaller scale.)
Cavendish the skeptic man he was, rigorously repeated the experiment and only after his health began failing in the winter of 1909 did he publish the results of his experiment. It was the only thing he felt enough about not to take with him into his grave.
Others scientist immediately understood the importance of his discovery, not in term of the obsolete phlogiston theory but the newly emerging atomic theory of Dalton. What he had done was more than incredible, Cavendish had realized the ancient dream of alchemist the transmutation of elements. Sure he had “only” turned nitrogen into air and hydrogen but nevertheless clearly everyone with an working mind could see the dawn of the new nuclear age. What actually happened was that alpha particles a form of radiation released by radioactive decay were allowed to pass through nitrogen gas, when one struck a nitrogen nucleus, a hydrogen nucleus was ejected, and an oxygen nucleus formed. Cavendish lived to be 78 and died quietly at home in 1810 before seeing the new world himself.
Notes and Sources
(1) In OTL 1898, two months before Marie Curie, Gerhard Carl Schmidt who used a photographic method similar to that of Becquerel discovered that thorium is radioactive. "Über die von den Thorverbindungen und einigen anderen Substanzen ausgehende Strahlung” (On the radiation emitted by thorium compounds and some other substances).
Marie Curie also wrote that "Uranium, thorium, polonium, radium, and their compounds make the air a conductor of electricity and act photographically on sensitive plates. In these respects, polonium and radium are considerably more active than uranium and thorium. On photographic plates one obtains good impressions with radium and polonium in a half-minute's exposure; several hours are needed to obtain the same result with uranium and thorium."
So a primitve photographic dosimeter should have worked for Klaproth. After cheking all alvailable sources to me it seems there was no Thorium in the known German uranium mines, so we will have to wait a bit until its found.
(2) In OTL the element is called Polonium. Here it is named after the German national hero Arminius/Hermann.
Marie and Pierre Curie and the Discovery of Polonium and Radium
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The KFM, A Homemade Yet Accurate and Dependable Fallout Meter.
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An unsing hero of science. (actual title)
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