Your challenge is to find a POD which could allow pre-modern civilizations to discover and produce on a useful scale Aluminum. Bonus points if you can do it in antiquity.
The challenges faced here are multiple:
First, the relative lack of native aluminum in the world, and the difficulty of going from "this material exists" to "this material can be made useful by an easy process." It occurs inside volcanoes. Not particularly helpful there. Iron from meteorites was known for millenia. Native copper happens sometimes. Copper in metallic form can be extracted from some clays in a very hot kiln, if native copper isn't available--indeed, that's likely how the Copper Age got started--a potter discovering copper residue in his kiln. Aluminum is typically produced from Al2O3 by a rather complex process involving a mineral most readily found in
Greenland.
And you need an electric current to then produce metallic aluminum. A crude voltaic pile could supply the needed voltage, but only at a very small current (V = IR). Which means not very much aluminum produced, even assuming that the apparatus needed to melt cryolite at around 1300 K is possible.
And where will they get ore? Bauxite? How would they stumble upon the technique of making alumina out of bauxite? They would need NaOH--which has its own set of technological challenges.
So what does that leave? It leaves digging cryolite out of Greenland (or elsewhere), towing it to your population center, heating it up, and dumping rubies and sapphires into the mixture, while plugging a dozen Baghdad Batteries into it to make a small amount of a metal that isn't as strong as (much more readily available) iron.
I'm going to say that a pre-modern Aluminum Age just isn't happening.